A team of Carnegie scientists led by Timothy Strobel has synthesized an entirely new form of silicon that promises even greater future applications.
The second, most abundant element in the Earth’s crust is silicon. When Silicon is purified, it takes on a structure that is comparable to a diamond. This is essential to modern electronic devices.
Although silicon is incredibly common in today’s technology, its so-called indirect band gap semiconducting properties prevent it from being considered for next-generation, high-efficiency applications such as light-emitting diodes, higher-performance transistors and certain photovoltaic devices.
Metallic substances conduct electrical current easily, whereas insulating (non-metallic) materials don’t conduct current at all. Semiconducting materials exhibit mid-range electrical conductivity, when they are subjected to an input of a specific energy, bound electrons can move to higher-energy, conducting states.
The specific energy required to make this jump to the conducting state is defined as the “band gap.” While direct band gap materials can effectively absorb and emit light, indirect band gap materials, like diamond-structured silicon, cannot.
Silicon’s band gap needs to be altered in order to make it more useful in new technology. Strobel and his team, which includes, Carnegie’s Duck Young Kim, Stevce Stefanoski and Oleksandr Kurakevych (now at Sorbonne) were able to synthesize a new form of silicon with a quasi-direct band gap that falls within the desired range for solar absorption, something that has never before been achieved.
The silicon the team has created is called an allotrope, which means a different physical form of the same element, in the same way that diamonds and graphite are both forms of carbon. Unlike the conventional diamond structure, this new silicon allotrope consists of an interesting open framework, called a zeolite-type structure, which is composed of channels with five, six and eight membered silicon rings.
The team created it using a novel high-pressure precursor process. First, a compound of silicon and sodium, Na4Si24, was formed under high-pressure conditions. Next this compound was recovered to ambient pressure, and the sodium was completely removed by heating under vacuum.
The resulting pure silicon allotrope, Si24, has the ideal band gap for solar energy conversion technology, and can absorb, and potentially emit, light far more effectively than conventional diamond-structured silicon. Si24 is stable at ambient pressure to at least 842 degrees Fahrenheit (450 degrees Celsius).
“High-pressure precursor synthesis represents an entirely new frontier in novel energy materials,” remarked Strobel. “Using the unique tool of high pressure, we can access novel structures with real potential to solve standing materials challenges. Here we demonstrate previously unknown properties for silicon, but our methodology is readily extendible to entirely different classes of materials. These new structures remain stable at atmospheric pressure, so larger-volume scaling strategies may be entirely possible.”
“This is an excellent example of experimental and theoretical collaboration,” said Kim. “Advanced electronic structure theory and experiment have converged to deliver a real material with exciting prospects. We believe that high-pressure research can be used to address current energy challenges, and we are now extending this work to different materials with equally exciting properties.”
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